All women and girls (or, if there isn't a woman in the house, the head of the household), light candles at least 18 minutes before sunset – see this link for the exact time – and recite the following blessings:
1) בָּרוּךְ אַתָּה אַדֹנָ-י אֱ-לֹהֵינוּ מֶלֶךְ הָעוֹלָם אֲשֶׁר קִדְּשָׁנוּ בְּמִצְוֹתָיו וְצִוָּנוּ לְהַדְלִיק נֵר שֶׁל (שַׁבָּת וְשֶׁל) יוֹם הַכִּפֻּרִים
Bah-rookh ah-tah ah-doh-noi eh-loh-hay-noo meh-lekh hah-oh-lahm, ah-shehr ki-deh-shah-noo beh-mitz-voh-tahv veh-tzee-vah-noo leh-hahd-lik nayr shehl [if Yom Kippur is on Shabbat add: shah-bahtveh-shehl] yohm hah-kee-poo-rim.
Blessed are You, L‑rd, our G‑d, King of the universe, who has sanctified us with His commandments and has commanded us to kindle the light of [if Yom Kippur is on Shabbat add: Shabbat and] Yom Kippur.
2) בָּרוּךְ אַתָּה אַדֹנָ-י אֱ-לֹהֵינוּ מֶלֶךְ הָעוֹלָם שֶׁהֶחֱיָנוּ וְקִיְּמָנוּ וְהִגִּיעָנוּ לִזְּמַן הַזֶּה
Bah-rookh ah-tah ah-doh-noi eh-loh-hay-noo meh-lekh hah-oh-lahm sheh-heh-kheh-yah-noo veh-kee-mah-noo ve-hig-ee-yah-noo liz-mahn hah-zeh.
Blessed are You, Lord our G‑d, King of the universe, who has granted us life, sustained us, and enabled us to reach this occasion.
If the one lighting the candles intends to drive to synagogue for the Kol Nidrei prayers, she should have in mind while lighting the candles that she is not just yet accepting upon herself the sanctity of the holiday. She should then immediately proceed to the synagogue, without undue delay.
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