The 191st prohibition is that we are forbidden from eating fresh grain from the new crop before the 16th of Nissan.
The source of this prohibition is G‑d's statement,1 " 'You may not eat bread, roasted grain or fresh grain until that day [when you bring this sacrifice to your G‑d]."
We have already quoted the statement of our Sages,2 "One who eats bread, roasted grain and fresh grain [from the new crop before the 16th of Nissan] is guilty for each one separately." We explained this very thoroughly in the Ninth Principle which preceded this work, see there.
The details of the laws regarding the new crop (chodosh) are explained in the 6th chapter of tractate Menachos, and in many passages of tractates Shvi'is, Ma'asros and Challah.