Chametz is any food product made from wheat, barley, rye, oats, spelt, or their derivatives, which has leavened (risen). Our sages have determined that flour from any of these five grains that comes in contact with water or moisture will leaven, unless fully baked within eighteen minutes. As we are commanded by the Torah, if a food contains even a trace of chametz, we don’t eat it, we don’t derive benefit from it, and we make sure not to have any of it in our possession for all the days of Passover.
To be certain that a product is kosher for Passover, it must have rabbinical certification. Otherwise it is possible that it contains chametz ingredients, or traces of chametz if it was processed on the same equipment as chametz products. Thus, unless a product is certified Kosher for Passover, we consider it chametz, and make sure not to have it in our possession on Passover.
Note: Matzah used all year round might be pure chametz, and not for Passover use. Only matzahs baked especially for Passover may be used on Passover.
(Corn is not one of those grains, but is not eaten of Passover by Ashkenazic as part of the rabbinic ban on what is know as kitniyot. See: chabad.org/871998)
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Yet, on Pesach, there is a long list of prohibited items under the category of Chametz; i.e any food product made from wheat, barley, rye, oats, spelt, or their derivatives, as well as corn.
Our ancestors did not have time to pick what they should bring along on the journey out of Egypt. They grabbed what they could, including their normal bread dough, and left. The key to achieving matzah was not in the contents of the dough, but in the process: limited leavening time and baking on hot desert rocks.
Why then do we have so much discussion on what is prohibited? None of the modern-day chametz was ever mentioned in the story of Exodus. The Almighty never spoke to Moses saying,"Lead our people Israel out of Egypt, but check them for wheat, barley, rye, oats, and spelt"
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